Search results for "thermal [radiation mechanism]"

Variation in clutch size in relation to nest size in birds

2014

© 2014 The Authors. Nests are structures built to support and protect eggs and/or offspring from predators, parasites, and adverse weather conditions. Nests are mainly constructed prior to egg laying, meaning that parent birds must make decisions about nest site choice and nest building behavior before the start of egg-laying. Parent birds should be selected to choose nest sites and to build optimally sized nests, yet our current understanding of clutch size-nest size relationships is limited to small-scale studies performed over short time periods. Here, we quantified the relationship between clutch size and nest size, using an exhaustive database of 116 slope estimates based on 17,472 nes…

Solid-State Synthesis of “Bamboo-Like” and Straight Carbon Nanotubes by Thermolysis of Hexa-peri-hexabenzocoronene–Cobalt Complexes

2006

Thermal stability, structural properties and catalytic activity of Pd catalysts supported on Al2O3–CeO2–BaO mixed oxides prepared by sol–gel method

2003

Abstract Al2O3–CeO2–BaO oxides with constant Al/Ba mass ratio and increasing cerium content were prepared, using the sol–gel procedure, and calcined at 1000 °C for 5 h. The influence of barium oxide on the thermal stability and on the morphological and structural properties of the corresponding supports, in terms of increasing surface area of alumina and ceria dispersion, was studied. The corresponding Pd (1 wt.%) catalysts were prepared by a stepwise impregnation method with a solution of palladium acetylacetonate in benzene. Palladium was introduced in two sequential steps by impregnation 0.5 wt.% of Pd each time. The structural and textural properties of the materials were studied by X-r…

Hydrothermal macroscopic Fe-sepiolite from Oujda Mounts (Middle Atlas, Eastern Morocco)

2008

The Triassic-Jurassic series in the Oujda Mounts (Middle Atlas, NE Morocco) includes two basaltic units. The whole sequence is crosscut by veins filled with Fe-sepiolite + chalcedony + calcite + smectite and mixed layer talc-saponite. Fe-sepiolite occurs as macroscopic fibres and is one of the latest mineral phases in the filling sequence of the veins. The compositional relationships and crystallographic parameters obtained on carefully selected samples of sepiolite are compared with previous data, and support the actual development of Mg-Fe substitution in this clay mineral, given the adequate hydrothermal conditions. Genesis of this uncommon variety of sepiolite in veins is interpreted as…

The compositional variability of eudialyte-group minerals

2011

AbstractEudialyte-group minerals (EGM) represent the most important index minerals of persodic agpaitic systems. Results are presented here of a combined EPMA, Mössbauer spectroscopy and LA-ICP-MS study and EGM which crystallized in various fractionation stages from different parental melts and mineral assemblages in silica over- and undersaturated systems are compared. Compositional variability is closely related to texture, allowing for reconstruction of locally acting magmatic to hydrothermal processes. Early-magmatic EGM are invariably dominated by Fe whereas hydrothermal EGM can be virtually Fe-free and form pure Mn end-members. Hence the Mn/Fe ratio is the most suitable fractionation …

Spectral, mineralogical, and geochemical variations across Home Plate, Gusev Crater, Mars indicate high and low temperature alteration

2009

Over the last ~3 years in Gusev Crater, Mars, the Spirit rover observed coherent variations in color, mineralogy, and geochemistry across Home Plate, an ~80 m-diameter outcrop of basaltic tephra. Observations of Home Plate from orbit and from the summit of Husband Hill reveal clear differences in visible/near-infrared (VNIR) colors between its eastern and western regions that are consistent with mineralogical compositions indicated by Mössbauer spectrometer (MB) and by Miniature Thermal Emission Spectrometer (Mini-TES). Pyroxene and magnetite dominate the east side, while olivine, nanophase Fe oxide (npOx) and glass are more abundant on the western side. Alpha Particle X-Ray Spectromet…

Steam and gas emission rate from La Soufriere volcano, Guadeloupe (Lesser Antilles): Implications for the magmatic supply during degassing unrest

2014

Abstract Since its last magmatic eruption in 1530 AD, La Soufriere andesitic volcano in Guadeloupe has displayed intense hydrothermal activity and six phreatic eruptive crises. Here we report on the first direct quantification of gas plume emissions from its summit vents, which gradually intensified during the past 20 years. Gas fluxes were determined in March 2006 and March 2012 by measuring the horizontal and vertical distributions of volcanic gas concentrations in the air-diluted plume and scaling to the speed of plume transport. Fluxes in 2006 combine real-time measurements of volcanic H2S concentrations and plume parameters with the composition of the hot (108.5 °C) fumarolic fluid at …

Halogens in Mafic and Intermediate-Silica Content Magmas

2018

As volatile and variably mobile components, halogens play key roles in magmatic, metasomatic, mineralizing, and volcanic processes by influencing the physical and chemical properties of melts, fluids, and minerals. Volcanic emission of halogens to the atmosphere leads to long- and short-term impacts on atmospheric chemistry that range from global perturbation of the stratospheric O3 budget to more localized life-threatening contamination of soils and fresh water. The concentrations of F, Cl, Br, and I in melts, fluids, and minerals provide crucial geochemical information and insights into magmatic processes ranging from partial melting to volcanic eruptions. Halogen research is useful for e…

First gas and thermal measurements at the frequently erupting Gamalama volcano (Indonesia) reveal a hydrothermally dominated magmatic system

2020

Abstract The first gas and thermal measurements at the summit of the Gamalama volcano indicate that the system is dominated by hydrothermal processes. This is highlighted by the prevalence of H2S over SO2 (H2S/SO2 = 2–8), a high CO2/SO2 ratio (76–201), and a low heat transfer (3.0 MW) to the surface. A relative variation in gas composition is observed along the degassing fracture zone, possibly due to partial S scrubbing. Despite this surface hydrothermal signature, the system exhibits high gas equilibrium temperatures (425–480 °C), indicating that fluids are not exclusively derived from a boiling hydrothermal aquifer, but also sourced by cooling and crystallizing basaltic magma at deep tha…

Mercury concentration, speciation and budget in volcanic aquifers: Italy and Guadeloupe (Lesser Antilles)

2009

Abstract Quantifying the contribution of volcanism to global mercury (Hg) emissions is important to understand the pathways and the mechanisms of Hg cycling through the Earth's geochemical reservoirs and to assess its environmental impacts. While previous studies have suggested that degassing volcanoes might contribute importantly to the atmospheric budget of mercury, little is known about the amount and behaviour of Hg in volcanic aquifers. Here we report on detailed investigations of both the content and the speciation of mercury in aquifers of active volcanoes in Italy and Guadeloupe Island (Lesser Antilles). In the studied groundwaters, total Hg (THg) concentrations range from 10 to 500…